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polyester : ウィキペディア英語版
polyester

Polyester is a category of polymers that contain the ester functional group in their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include naturally occurring chemicals, such as in the cutin of plant cuticles, as well as synthetics through step-growth polymerization such as polybutyrate. Natural polyesters and a few synthetic ones are biodegradable, but most synthetic polyesters are not. This material is used very widely in clothing.
Depending on the chemical structure, polyester can be a thermoplastic or thermoset. There are also polyester resins cured by hardeners; however, the most common polyesters are thermoplastics.
Fabrics woven or knitted from polyester thread or yarn are used extensively in apparel and home furnishings, from shirts and pants to jackets and hats, bed sheets, blankets, upholstered furniture and computer mouse mats. Industrial polyester fibers, yarns and ropes are used in tyre reinforcements, fabrics for conveyor belts, safety belts, coated fabrics and plastic reinforcements with high-energy absorption. Polyester fiber is used as cushioning and insulating material in pillows, comforters and upholstery padding. Polyester fabrics are highly stain-resistant— in fact, the only class of dyes which ''can'' be used to alter the color of polyester fabric are what are known is disperse dyes.
Polyester fibers are sometimes spun together with natural fibers to produce a cloth with blended properties. Cotton mixed with Polyester blends can be strong, wrinkle and tear-resistant, and reduce shrinking. Synthetic fibers in polyester also create materials with water, wind and environmental resistance compared to plant-derived fibers. Cons of cotton and polyester blends include being less breathable than cotton and trapping more moisture while sticking to the skin. They are also less fire resistant and can melt when ignited.
Polyester blends have been renamed so as to suggest their similarity or even superiority to natural fibers (for example, China silk, which is a term in the textiles industry for a 100% polyester fiber woven to resemble the sheet and durability of insect-derived silk).
Polyesters are also used to make bottles, films, tarpaulin, canoes, liquid crystal displays, holograms, filters, dielectric film for capacitors, film insulation for wire and insulating tapes. Polyesters are widely used as a finish on high-quality wood products such as guitars, pianos and vehicle/yacht interiors. Thixotropic properties of spray-applicable polyesters make them ideal for use on open-grain timbers, as they can quickly fill wood grain, with a high-build film thickness per coat. Cured polyesters can be sanded and polished to a high-gloss, durable finish.
Liquid crystalline polyesters are among the first industrially used liquid crystal polymers. They are used for their mechanical properties and heat-resistance. These traits are also important in their application as an abradable seal in jet engines.
==Types==
Polyesters as thermoplastics may change shape after the application of heat. While combustible at high temperatures, polyesters tend to shrink away from flames and self-extinguish upon ignition. Polyester fibers have high tenacity and E-modulus as well as low water absorption and minimal shrinkage in comparison with other industrial fibers.
Unsaturated polyesters (UPR) are thermosetting resins. They are used as casting materials, fiberglass laminating resins and non-metallic auto-body fillers. Fiberglass-reinforced unsaturated polyesters find wide application in bodies of yachts and as body parts of cars.
According to the composition of their main chain, polyesters can be:
Increasing the aromatic parts of polyesters increases their glass transition temperature, melting temperature, thermal stability, chemical stability...
Polyesters can also be telechelic oligomers like the polycaprolactone diol (PCL) and the polyethylene adipate diol (PEA). They are then used as prepolymers.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「polyester」の詳細全文を読む



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