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isophorone : ウィキペディア英語版
isophorone

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Isophorone is an α,β-unsaturated cyclic ketone, a colorless to yellowish liquid with a characteristic peppermint-like smell. It is used as a solvent and as an intermediate in organic synthesis. Isophorone also occurs naturally in cranberries.〔 (Chronic Toxicity Summary )〕
==Production==
Isophorone can be manufactured by catalyzed self-condensation of acetone.〔 〕
Mesityl oxide is the initial product of the self-aldol condensation of acetone. The mesityl oxide formed can react further with acetone via a Michael reaction and subsequent intramolecular aldol condensation to eventually obtain the six-membered ring of isophorone. This is an example of the Robinson annulation. The yield of the two compounds depends on the reaction conditions.
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抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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