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halocarbon : ウィキペディア英語版
halocarbon
Halocarbon compounds are chemicals in which one or more carbon atoms are linked by covalent bonds with one or more halogen atoms (fluorine, chlorine, bromine or iodine – ) resulting in the formation of organofluorine compounds, organochlorine compounds, organobromine compounds, and organoiodine compounds. Chlorine halocarbons are the most common and are called organochlorides.〔Yoel Sasson. "Formation of Carbon–Halogen Bonds (Cl, Br, I)" in Patai's ''Chemistry of Functional Groups'' (2009). Wiley-VCH, Weinheim. 〕
Many synthetic organic compounds such as plastic polymers, and a few natural ones, contain halogen atoms; they are known as ''halogenated'' compounds or ''organohalogens''. Organochlorides are the most common industrially used organohalides, although the other organohalides are used commonly in organic synthesis. Except for extremely rare cases, organohalides are not produced biologically, but many pharmaceuticals are organohalides. Notably, many pharmaceuticals such as Prozac have trifluoromethyl groups.
For information on inorganic halide chemistry, see halide.
== Chemical families ==

Halocarbons are typically classified in the same ways as the similarly structured organic compounds that have hydrogen atoms occupying the molecular sites of the halogen atoms in halocarbons. Among the chemical families are:〔M. Rossberg et al. “Chlorinated Hydrocarbons” in Ullmann’s Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. 〕
*haloalkanes—compounds with carbon atoms linked by single bonds
*haloalkenes—compounds with one or more double bonds between carbon atoms
*haloaromatics—compounds with carbons linked in one or more aromatic rings with a delocalised donut shaped pi cloud.
The halogen atoms in halocarbon molecules are often called "substituents," as though those atoms had been substituted for hydrogen atoms. However halocarbons are prepared in many ways that do not involve direct substitution of halogens for hydrogens.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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