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halogen : ウィキペディア英語版
halogen

The halogens or halogen elements () are a group in the periodic table consisting of five chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At). The artificially created element 117 (ununseptium) may also be a halogen. In the modern IUPAC nomenclature, this group is known as group 17.
The name 'halogen' means 'salt-producing'. When halogens react with metals they produce a wide range of salts, including calcium fluoride, sodium chloride (common salt), silver bromide and potassium iodide.
The group of halogens is the only periodic table group that contains elements in three of the four main states of matter at standard temperature and pressure. All of the halogens form acids when bonded to hydrogen. Most halogens are typically produced from minerals or salts. The middle halogens, that is chlorine, bromine and iodine, are often used as disinfectants. Organobromides are the most important class of flame retardants. Elemental halogens are lethally to dangerously toxic.
== History ==
The fluorine mineral fluorospar was known as early as 1529. Early chemists realized that fluorine compounds contain an undiscovered element, but were unable to isolate it. In 1869, George Gore, an English chemist, ran a current of electricity through hydrofluoric acid and discovered fluorine, but he was unable to prove his results at the time. In 1886, Henri Moissan, a chemist in Paris, performed electrolysis on potassium bifluoride dissolved in waterless hydrofluoric acid, and successfully produced fluorine.
Hydrochloric acid was known to alchemists and early chemists. However, elemental chlorine was not produced until 1774, when Carl Wilhelm Scheele heated hydrochloric acid with manganese dioxide. Scheele called the element "dephlogisticated muriatic acid", which is how chlorine was known for 33 years. In 1807, Humphry Davy investigated chlorine and discovered that it is an actual element. Chlorine was used as a poison gas during World War I.〔
Bromine was discovered in the 1820s by Antoine-Jérôme Balard. Balard discovered bromine by passing chlorine gas through a sample of brine. He originally proposed the name ''muride'' for the new element, but the French Academy changed the element's name to bromine.〔
Iodine was discovered by Bernard Courtois, who was using seaweed ash as part of a process for saltpeter manufacture. Courtois typically boiled the seaweed ash with water to generate potassium chloride. However, in 1811, Courtois added sulfuric acid to his process, and found that his process produced purple fumes that condensed into black crystals. Suspecting that these crystals were a new element, Courtois sent samples to other chemists for investigation. Iodine was proven to be a new element by Joseph Gay-Lussac.〔
In 1931, Fred Allison claimed to have discovered element 85 with a magneto-optical machine, and named the element Alabamine, but was mistaken. In 1937, Jajendralal De claimed to have discovered element 85 in minerals, and called the element dakine, but he was also mistaken. An attempt at discovering element 85 in 1939 by Horia Hulublei and Yvette Cauchois via spectroscopy was also unsuccessful, as was an attempt in the same year by Walter Minder, who discovered an iodine-like element resulting from beta decay of radium. Element 85, now named astatine, was produced successfully in 1940 by Dale R. Corson, K.R. Mackenzie, and Emilio G. Segrè, who bombarded bismuth with alpha particles.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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