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diketene : ウィキペディア英語版
diketene

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Diketene is an organic compound with the formula (CH2CO)2. It is formed by dimerization of ketene (IUPAC name: ethenone). Diketene is a member of the oxetane family. It is used as a reagent in organic chemistry.〔Beilstein E III/IV 17: 4297.〕 It is a colorless liquid.
==Production==
Ketene is generated by dehydrating acetic acid at 700–750 °C in the presence of triethyl phosphate as a catalyst or (in Switzerland and the CIS) by the thermolysis of acetone at 600–700 °C in the presence of carbon disulfide as a catalyst.〔
:CH3CO2H → H2C=C=O + H2O (Δ''H'' = +147 kJ/mol)
:CH3COCH3 → H2C=C=O + CH4

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