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cycloaddition : ウィキペディア英語版
cycloaddition
A cycloaddition is a pericyclic chemical reaction, in which "two or more unsaturated molecules (or parts of the same molecule) combine with the formation of a cyclic adduct in which there is a net reduction of the bond multiplicity."〔(【引用サイトリンク】title=Cycloaddition )〕 The resulting reaction is a cyclization reaction. Many but not all cycloadditions are concerted. As a class of addition reaction, cycloadditions permit carbon–carbon bond formation without the use of a nucleophile or electrophile.
Cycloadditions can be described using two systems of notation. An older, but still common, notation is based on the size of linear arrangements of atoms in the reactants. It uses parentheses: (''i'' + ''j'' + …) where the variables are the numbers of linear atoms in each reactant. The product is a cycle of size (''i'' + ''j'' + …). In this system, the standard Diels-Alder reaction a (4 + 2)cycloaddition, the 1,3-dipolar cycloaddition is a (3 + 2)cycloaddition and cyclopropanation of a carbene with an alkene a (2 + 1)cycloaddition.〔
A more recent, IUPAC-preferred notation uses square brackets to indicate the number of ''electrons'', rather than carbon atoms, involved in the formation of the product. In the (+ ''j'' + … ) notation, the standard Diels-Alder reaction is a (+ 2 )cycloaddition, the 1,3-dipolar cycloaddition is (+ 2 ).〔
==Thermal cycloadditions and their stereochemistry==
Thermal cycloadditions are those cycloadditions where the reactants are in the ground electronic state. They usually have (4''n'' + 2) π electrons participating in the starting material, for some integer n. These reactions occur, for reasons of orbital symmetry, in a suprafacial-suprafacial or antarafacial-antarafacial manner (rare). There are a few examples of thermal cycloadditions which have 4''n'' π electrons (for example the (+ 2 ) cycloaddition); these proceed in a suprafacial-antarafacial sense, such as the dimerisation of ketene, in which the orthogonal set of p orbitals allows the reaction to proceed via a crossed transition state.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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