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| Section2 = }} Thiocyanogen, (SCN)2, is a pseudohalogen derived from the pseudohalide thiocyanate, ()−. This hexatomic compound exhibits C2 point group symmetry and has the connectivity NCS-SCN. The oxidation ability is greater than bromine. It reacts with water: (SCN)2 + H2O → HSCN + HSCNO Thiocyanogen was originally prepared by the reaction of iodine with a suspension of silver thiocyanate in diethyl ether, but this reaction suffers from competing equilibria attributed to the weak oxidizing power of iodine. An improved method for generating thiocyanogen entails oxidation of plumbous thiocyanate, which precipitates when aqueous solutions of lead(II) nitrate and sodium thiocyanate are combined. A suspension of anhydrous Pb(SCN)2 is treated with bromine in glacial acetic acid to afford a 0.1M solution of thiocyanogen that is stable for days. Alternatively, a solution of bromine in methylene chloride is added dropwise to a suspension of Pb(SCN)2 in methylene chloride at 0 °C followed by filtration under argon to give a solution of thiocyanogen that should be used immediately. :Pb(SCN)2 + Br2 → (SCN)2 + PbBr2 Thiocyanogen adds to alkenes to give 1,2-bis(thiocyanato) compounds and reacts with titanacyclopentadienes giving (''Z'',''Z'')-1,4-bis(thiocyanato)-1,3-butadienes, which in turn can be converted to 1,2-dithiins.〔 Selenocyanogen, (SeCN)2, prepared from reaction of silver selenocyanate with iodine in tetrahydrofuran at 0 °C, reacts in a similar manner to thiocyanogen.〔 ==References== 〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Thiocyanogen」の詳細全文を読む スポンサード リンク
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