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・ Thiosulfoxide
・ Thiosulfuric acid
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・ Thiocarbohydrazide
・ Thiocarbonate
・ Thiocarbonic acid
・ Thiocarboxylic acid
・ Thiocarlide
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・ Thiocyanate
・ Thiocyanate hydrolase
・ Thiocyanate isomerase
Thiocyanatoiron
・ Thiocyanic acid
・ Thiocyanogen
・ Thiodia
・ Thiodia citrana
・ Thiodia glandulosana
・ Thiodia lerneana
・ Thiodia torridana
・ Thiodiglycol
・ Thiodina
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・ Thioescaline
・ Thioester
・ Thioester-containing protein 1


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Thiocyanatoiron : ウィキペディア英語版
Thiocyanatoiron

Thiocyanatoiron (systematically named thiocyanatoiron(2+)) is a inorganic cation with the chemical formula ()2+. It is known to produce a blood red color in solution. This is used as a test for Fe3+ in the laboratory. Fe3+ reacts with thiocyanate to give a series of intensely red colored compounds which remain in the solution and does not undergo any reaction after the formation of the stable octahedral structure. In high concentration of SCN the compound is fairly octahedral with six thiocyanate ligands bonded to iron atom. Thiocyanatoiron forms a pentahydrate.
Thiocyanatoiron must be stored in an acidic solution to prevent the formation of FeOH2+ ions. The excess H+ ions in the acidic solution prevent Fe3+ from engaging in side reactions. Thiocyanatoiron decomposes with exposure to light. The thiocyanatoiron ion is usually formed through an equilibrium reaction:

:Fe3+(aq) + SCN(aq) ↔ ()2+(aq)
== Chemical properties ==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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