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・ Tetramethylammonium chloride
・ Tetramethylammonium hydroxide
・ Tetramethylammonium pentafluoroxenate
・ Tetramethylammonium-corrinoid protein Co-methyltransferase
・ Tetramethylazodicarboxamide
・ Tetramethylbenzenes
・ Tetramethylbutane
・ Tetramethyldiborane
・ Tetramethylenedisulfotetramine
・ Tetramethylethylenediamine
・ Tetramethylethylenediamine (data page)
・ Tetramethylpyrazine
・ Tetramethylsilane
・ Tetramethylsuccinonitrile
・ Tetramethyltetrahydrofuran
Tetramethyltin
・ Tetramethyluric acid
・ Tetramicra
・ Tetramicra (orchid)
・ Tetramine
・ Tetramitus
・ Tetramoera
・ Tetramoera schistaceana
・ Tetramolopium
・ Tetramolopium arenarium
・ Tetramolopium capillare
・ Tetramolopium filiforme
・ Tetramolopium lepidotum
・ Tetramolopium remyi
・ Tetramolopium rockii


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Tetramethyltin : ウィキペディア英語版
Tetramethyltin

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Tetramethyltin is an organometallic compound with the formula (CH3)4Sn. This liquid, one of the simplest organotin compounds, is useful for transition-metal mediated conversion of acid chlorides to methyl ketones and aryl halides to aryl methyl ketones. It is volatile and toxic, so care should be taken when using it in the laboratory.
==Synthesis and structure==
Tetramethyltin is synthesized by reaction of the Grignard reagent methylmagnesium iodide, with SnCl4, which is synthesized by reacting tin metal with chlorine gas.
:4 CH3MgI + SnCl4 → (CH3)4Sn + 4 MgICl
In tetramethyltin, the metal surrounded by four methyl groups in a tetrahedral structure is a heavy analogue of neopentane.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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