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Polyisoprene : ウィキペディア英語版
Synthetic rubber
Synthetic rubber, invariably a polymer, is any type of artificial elastomer mainly synthesised from petroleum byproducts. An elastomer is a material with the mechanical (or material) property that it can undergo much more elastic deformation under stress than most materials and still return to its previous size without permanent deformation. About 15 billion kilograms of rubbers are produced annually, and of that amount two thirds is synthetic. Global revenues generated with synthetic rubbers are likely to rise to approximately US$56 billion in 2020. Synthetic rubber, like natural rubber, has uses in the automotive industry for tires, door and window profiles, hoses, belts, matting, and flooring.
==Natural vs. synthetic rubber==

Natural rubber, coming from latex of ''Hevea brasiliensis'', is mainly poly-''cis''-isoprene containing traces of impurities like protein, dirt etc. Although it exhibits many excellent properties in terms of mechanical performance, natural rubber is often inferior to certain synthetic rubbers, especially with respect to its thermal stability and its compatibility with petroleum products.
Synthetic rubber is made by the polymerization of a variety of petroleum-based precursors called monomers. The most prevalent synthetic rubbers are styrene-butadiene rubbers (SBR) derived from the copolymerization of styrene and 1,3-butadiene. Other synthetic rubbers are prepared from isoprene (2-methyl-1,3-butadiene), chloroprene (2-chloro-1,3-butadiene), and isobutylene (methylpropene) with a small percentage of isoprene for cross-linking. These and other monomers can be mixed in various proportions to be copolymerized to produce products with a range of physical, mechanical, and chemical properties. The monomers can be produced pure and the addition of impurities or additives can be controlled by design to give optimal properties. Polymerization of pure monomers can be better controlled to give a desired proportion of ''cis'' and ''trans'' double bonds.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Synthetic rubber」の詳細全文を読む



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