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Isobutyraldehyde
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Isobutyraldehyde : ウィキペディア英語版
Isobutyraldehyde

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Isobutyraldehyde is the chemical compound with the formula (CH3)2CHCHO. It is an aldehyde, isomeric with n-butyraldehyde (butanal).〔Isobutyraldehyde is a retained trivial name under the IUPAC rules.〕 Isobutyraldehyde is manufactured, often as a side-product, by the hydroformylation of propene. Its odour is described as that of wet cereal or straw. It undergoes the Cannizaro reaction even though it has alpha hydrogen atom.
==Synthesis==
Isobutyraldehyde is produced industrially by the hydroformylation of propene. Several million tons are produced annually. 〔Boy Cornils, Richard W. Fischer, Christian Kohlpaintner "Butanals" in Ullmann's Encyclopedia of Industrial Chemistry, 2000, Wiley-VCH, Weinheim. 〕
Strong mineral acids catalyse the rearrangement of methallyl alcohol to isobutraldehyde.
It can also be produced using engineered bacteria.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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