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Decamethylferrocene : ウィキペディア英語版
Decamethylferrocene

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Decamethylferrocene is a sandwich compound. In terms of structure and bonding it resembles ferrocene, but with a methyl group on each of the carbons of the Cp rings. It is a yellow crystalline solid that is a weak reductant.
== Preparation ==
Decamethylferrocene is prepared in the same manner as ferrocene from pentamethylcyclopentadiene. This method can be used to produce other decamethylcyclopentadienyl sandwich compounds.
:2 Li(C5Me5) + FeCl2 → Fe(C5Me5)2 + 2 LiCl
The product can be purified by sublimation. FeCp2
* has staggered Cp
* rings. The average distance between iron and each carbon is approximately 2.050 Å. This structure has been confirmed by X-ray crystallography.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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