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Decamethylcobaltocene
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Decamethylcobaltocene : ウィキペディア英語版
Decamethylcobaltocene

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Decamethylcobaltocene is an organocobalt compound with the formula Co(C5(CH3)5)2, abbreviated CoCp
*2. It is a dark brown solid. This compound is used as a strong reducing agent in organometallic chemistry.
== Synthesis ==
Decamethylcobaltocene is prepared by treatment of LiCp
* with CoCl2:
:2 LiCp
* + CoCl2 → 2 LiCl + CoCp
*2
The permethylated form is more air-sensitive than the parent cobaltocene, owing to the inductive effects of methyl groups. It is a thermally stable compound and easily undergoes vacuum sublimation.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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