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salicylaldehyde : ウィキペディア英語版
salicylaldehyde

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Salicylaldehyde (2-hydroxybenzaldehyde) is the organic compound with the formula C6H4CHO-2-OH.〔''Merck Index'', 11th Edition, 8295〕 Along with 3-hydroxybenzaldehyde and 4-hydroxybenzaldehyde, it is one of the three isomers of hydroxybenzaldehyde. This colorless oily liquid has a bitter almond odor at higher concentration. Salicylaldehyde is a key precursor to a variety chelating agents, some of which are commercially important.
== Production ==
Salicylaldehyde is prepared from phenol and chloroform by heating with sodium hydroxide or potassium hydroxide in a Reimer–Tiemann reaction:
:
Alternative, it is produced by condensation of phenol or its derivatives with formaldehyde to give hydroxybenzyl alcohol, which is oxidized to the aldehyde.
Salicylaldehydes in general may be prepared from the corresponding phenol by the Duff reaction, or by treatment with paraformaldehyde in the presence of magnesium chloride and a base.

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