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polyaniline : ウィキペディア英語版
polyaniline
Polyaniline (PANI) is a conducting polymer of the semi-flexible rod polymer family. Although the compound itself was discovered over 150 years ago, only since the early 1980s has polyaniline captured the intense attention of the scientific community. This interest is due to the rediscovery of high electrical conductivity. Amongst the family of conducting polymers and organic semiconductors, polyaniline has many attractive processing properties. Because of its rich chemistry, polyaniline is one of the most studied conducting polymers of the past 50 years.〔Okamoto, Yoshikuko and Brenner, Walter (1964) "Polymers", Ch. 7 pp. 125–158 in ''Organic Semiconductors'', Reinhold.〕
==History==
As described by Alan MacDiarmid, the first definitive report of polyaniline did not occur until 1862, which included an electrochemical method for the determination of small quantities of aniline.
From the early 20th century on, occasional reports about the structure of PANI were published. Subsequent to his investigation of other highly-conductive organic materials, MacDiarmid demonstrated the conductive states of polyaniline which arose upon protonic doping of the emeraldine form of polyaniline. Conductive polymers such as polyaniline remain of widespread interest, providing an opportunity to address fundamental issues of importance to condensed matter physics, including, for example, the metal-insulator transition, the Peierls Instability and quantum decoherence.

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