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orcinol : ウィキペディア英語版
orcinol

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Orcinol is a natural phenolic organic compound that occurs in many species of lichens〔Robiquet: „Essai analytique des lichens de l’orseille“, ''Annales de chimie et de physique'', 1829, ''42'', p. 236–257.〕 including ''Roccella tinctoria'' and ''Lecanora''. Orcinol has been detected in the "toxic glue" of the ant species ''Camponotus saundersi''.
== Chemistry ==
It can be formed by fusing extract of aloes with potash.
It is used in the production of the dye orcein and as a reagent in some chemical tests for pentoses, such as Bial's Test. It may be synthesized from toluene; more interesting is its production when acetone dicarboxylic ester is condensed with the aid of sodium. It crystallizes in colorless prisms with one molecule of water, which redden on exposure to air. Ferric chloride gives a bluish-violet coloration with the aqueous solution. Unlike resorcinol it does not give a fluorescein with phthalic anhydride. Oxidation of the ammoniacal solution gives orcein, C28H24N2O7, the chief constituent of the natural dye archil. Homo-pyrocatechin is an isomer (CH1: OH: OH= 1 3 :4), found as its methyl ether (creosol) in beech-wood tar.
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抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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