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diphenylacetylene : ウィキペディア英語版
diphenylacetylene

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Diphenylacetylene is the chemical compound C6H5C≡CC6H5. The molecule consists of phenyl groups attached to both ends of an alkyne. It is a colorless crystalline material that is widely used as a building block in organic synthesis and as a ligand in organometallic chemistry.
==Preparation==
Several preparations for this compound exist:
* benzil is condensed with hydrazine to give the bis(hydrazone), which is oxidized with mercury oxide.
* stilbene is brominated, then dehydrohalogenated, but the product can be contaminated with stilbene, which is difficult to remove.〔
* One method starts from iodobenzene and the copper salt of phenylacetylene in the Castro-Stephens coupling

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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