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dimethylamine : ウィキペディア英語版
dimethylamine

|Section2=〕
| Formula = (CH3)2NH
| Appearance = Colorless gas
| Odor = Fishy, ammoniacal
| Density = 649.6 kg m−3 (at 25 °C)
| MeltingPtK = 180.15
| BoilingPtK = 280 to 282
| Solubility = 3.540 kg L−1
| LogP = −0.362
| VaporPressure = 170.3 kPa (at 20 °C)
| HenryConstant = 310 μmol Pa−1 kg−1
| pKa = 10.64
| pKb = 3.29
}}
|Section3=
|Section4=
|Section5=
}}
Dimethylamine is an organic compound with the formula (CH3)2NH. This secondary amine is a colorless, flammable gas with an ammonia-like odor. Dimethylamine is commonly encountered commercially as a solution in water at concentrations up to around 40%. In 2005, an estimated 270,000 tons were produced industrially,〔A. B. van Gysel, W. Musin "Methylamines" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2005 Wiley-VCH Verlag, Weinheim. 〕 but it is also found as a natural product.
==Structure and properties==
The molecule consists of a nitrogen atom with two methyl substituents and one proton. Dimethylamine is a weak base and the pKa of the ammonium salt CH3-NH2+-CH3 is 10.73, a value above methylamine (10.64) and trimethylamine (9.79).
Dimethylamine reacts with acids to form salts, such as dimethylamine hydrochloride, an odorless white solid with a melting point of 171.5 °C. Dimethylamine is produced by catalytic reaction of methanol and ammonia at elevated temperatures and high pressure:〔

:2 CH3OH + NH3 → (CH3)2NH + 2 H2O

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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