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dimethoxymethane : ウィキペディア英語版
dimethoxymethane

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Dimethoxymethane, also called methylal, is a colorless flammable liquid with a low boiling point, low viscosity and excellent dissolving power. It has a chloroform-like odor and a pungent taste. It is the dimethyl acetal of formaldehyde. Dimethoxymethane is soluble in three parts water and miscible with most common organic solvents.
==Synthesis and structure==
It can be manufactured by oxidation of methanol or by the reaction of formaldehyde with methanol. In aqueous acid, it is hydrolyzed back to formaldehyde and methanol.
Due to the anomeric effect, dimethoxymethane has a preference toward the ''gauche'' conformation around the C–O bonds, instead of the ''anti'' conformation. Since it is one of the smallest molecules exhibiting this effect, which has great interest in carbohydrate chemistry, dimethoxymethane is often used for theoretical studies of the anomeric effect.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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