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decalin : ウィキペディア英語版
decalin

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Decalin (decahydronaphthalene, also known as bicyclo()decane), a bicyclic organic compound, is an industrial solvent. A colorless liquid with an aromatic odor, it is used as a solvent for many resins or fuel additives. It is the saturated analog of naphthalene and can be prepared from it by hydrogenation in a fused state in the presence of a catalyst. Decahydronaphthalene easily forms explosive organic peroxides upon storage in the presence of air.
== Isomers ==
Decahydronaphthalene occurs in cis and trans forms. The trans form is energetically more stable because of fewer steric interactions. ''Cis''-decalin is a chiral molecule without a chiral center; it has a two-fold rotational symmetry axis going through the center of the 1-6 bond, but no reflective symmetry. However, the chirality is canceled through a chair-flipping process that turns the molecule into its mirror image.

Image:Cis-trans isomerism of decahydronaphthalene.png|
1: ''trans'' (left) and ''cis'' (right) isomers

Image:Cis-decalin-3D-balls.png|2:
ball-and-stick model of ''cis''-decalin

Image:Trans-decalin-3D-balls.png|3:
''trans''-decalin

File:Cisdecalin conformations.png|4:
''cis''-decalin ring-flip



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「decalin」の詳細全文を読む



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