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cyclopentadiene : ウィキペディア英語版
cyclopentadiene

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Cyclopentadiene is an organic compound with the formula C5H6. This colorless liquid has a strong and unpleasant odor. At room temperature, this cyclic diene dimerizes over the course of hours to give dicyclopentadiene via a Diels–Alder reaction. This dimer can be restored by heating to give the monomer.
The compound is mainly used for the production of cyclopentene and its derivatives. It is popularly used as a precursor to the cyclopentadienyl ligand (Cp) in cyclopentadienyl complexes in organometallic chemistry.〔Hartwig, J. F. Organotransition Metal Chemistry, from Bonding to Catalysis; University Science Books: New York, 2010. ISBN 1-891389-53-X.〕
==Production and reactions==
Cyclopentadiene production is usually not distinguished from dicyclopentadiene since they are interconverted. They are obtained from coal tar (about 10 – 20 g/ton) and by steam cracking of Naphtha (about 14 kg/ton).〔 To obtain cyclopentadiene monomer, commercial dicyclopentadiene is cracked by heating to ~ 180 °C. The monomer is collected by distillation, and used soon thereafter.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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