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carbide : ウィキペディア英語版
carbide

In chemistry, a carbide is a compound composed of carbon and a less electronegative element. Carbides can be generally classified by chemical bonding type as follows: (i) salt-like, (ii) covalent compounds, (iii) interstitial compounds, and (iv) "intermediate" transition metal carbides. Examples include calcium carbide (CaC2), silicon carbide (SiC), tungsten carbide (WC) (often called simply ''carbide'' when referring to machine tooling), and cementite (Fe3C), each used in key industrial applications. The naming of ionic carbides is not systematic.
==Salt-like (saline) carbides==
Salt-like carbides are composed of highly electropositive elements such as the alkali metals, alkaline earth metals, and group 3 metals including scandium, yttrium and lanthanum. Aluminium from group 13 forms carbides, but gallium, indium and thallium do not. These materials feature isolated carbon centers, often described as "C4−", in the methanides or methides; two-atom units, "C22−", in the acetylides; and three-atom units, "C34−", in the sesquicarbides.〔 The graphite intercalation compound KC8, prepared from vapour of potassium and graphite, and the alkali metal derivatives of C60 are not usually classified as carbides.〔Shriver and Atkins — Inorganic Chemistry〕

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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