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acetonitrile : ウィキペディア英語版
acetonitrile

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Acetonitrile is the chemical compound with the formula . This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed as organic). It is produced mainly as a byproduct of acrylonitrile manufacture. It is used as a polar aprotic solvent in organic synthesis and in the purification of butadiene.〔(), Ashford's Dictionary of Industrial Chemicals, Third edition, 2011, page 76.〕
In the laboratory, it is used as a medium-polarity solvent that is miscible with water and a range of organic solvents, but not saturated hydrocarbons. It has a convenient liquid range and a high dielectric constant of 38.8. With a dipole moment of 3.92 D,〔Steiner, P. A., and Gordy, W., 1966, J. molec. Spectrosc., 21, 291.〕 acetonitrile dissolves a wide range of ionic and nonpolar compounds and is useful as a mobile phase in HPLC and LC-MS. The N-C-C skeleton is linear with a short C-N distance of 1.16 Å.
Acetonitrile was first prepared in 1847 by the French chemist Jean-Baptiste Dumas.
==Applications==
Acetonitrile is used mainly as a solvent in the purification of butadiene in refineries.
It is widely used in battery applications because of its relatively high dielectric constant and ability to dissolve electrolytes. For similar reasons it is a popular solvent in cyclic voltammetry.
Its ultraviolet transparency UV cutoff, low viscosity and low chemical reactivity make it a popular choice for high-performance liquid chromatography (HPLC).
Acetonitrile plays a significant role as the dominant solvent used in the manufacture of DNA oligonucleotides from monomers.
Industrially, it is used as a solvent for the manufacture of pharmaceuticals and photographic film.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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