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Reptation is the thermal motion of very long linear, ''entangled'' macromolecules in polymer melts or concentrated polymer solutions. Derived from the word reptile, reptation suggests the movement of entangled polymer chains as being analogous to snakes slithering through one another. Pierre-Gilles de Gennes introduced (and named) the concept of reptation into polymer physics in 1971 to explain the dependence of the mobility of a macromolecule on its length. Reptation is used as a mechanism to explain viscous flow in an amorphous polymer. Sir Sam Edwards and Masao Doi later refined reptation theory. Similar phenomena also occur in proteins. Two closely related concepts are Reptons and Entanglement. A repton is a mobile point residing in the cells of a lattice, connected by bonds. Entanglement means the topological restriction of molecular motion by other chains. ==Theory and mechanism== Reptation theory describes the effect of polymer chain entanglements on the relationship between molecular mass and chain relaxation time (or similarly, the polymer’s zero-shear viscosity). The theory predicts that, in entangled systems, the relaxation time is proportional to the cube of molecular mass, : . This is a reasonable approximation of the actual observed relationship, . The prediction of the theory is arrived at by a relatively simple argument. First, each polymer chain is envisioned as occupying a tube of length , through which it may move with snake-like motion (creating new sections of tube as it moves). Furthermore, if we consider a time scale comparable to , we may focus on the overall, global motion of the chain. Thus, we define the tube mobility as :, where is the velocity of the chain when it is pulled by a force, . Note also that will be inversely proportional to the degree of polymerization (and thus also inversely proportional to chain weight). The diffusivity of the chain through the tube may then be written as :. By then recalling that in 1-dimension the mean squared displacement due to Brownian motion is given by :, we obtain :. The time necessary for a polymer chain to displace the length of its original tube is then :. By noting that this time is comparable to the relaxation time, we establish that . Since the length of the tube is proportional to the degree of polymerization, and μtube is inversely proportional to the degree of polymerization, we observe that (and so ). From the preceding analysis, we see that molecular mass has a very strong effect on relaxation time in entangled polymer systems. Indeed, this is significantly different from the untangled case, where relaxation time is observed to be proportional to molecular mass. This strong effect can be understood by recognizing that, as chain length increases, the number of tangles present will dramatically increase. These tangles serve to reduce chain mobility. The corresponding increase in relaxation time can result in viscoelastic behavior, which is often observed in polymer melts. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Reptation」の詳細全文を読む スポンサード リンク
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