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Polydiacetylenes : ウィキペディア英語版
Polydiacetylenes

Polydiacetylenes (PDAs) are a family of conducting polymers closely related to polyacetylene. They are created by the 1,4 topochemical polymerization of diacetylenes. They have multiple applications from the development of organic films to immobilization of other molecules
==History==
The first polydiacetylene to be discovered was Poly(1,6-bishydroxy hexa-2,4-diacetylene) by Gerhard Wegner in 1969. This was achieved by exposing crystals of 1,6-bishydroxy hexa-2,4-diyne to UV light. Polymerization was assumed to occur because of the spatial arrangement of diynes in the crystal, but this was not confirmed until 1972 when Raymond H. Baughman coined the term "topochemical polymerization" to describe polymerization due to spatial arrangement and put forth the spatial requirements needed for a polymerization of this sort.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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