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・ Hexamitoptera lawinda
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Hexanitrohexaazaisowurtzitane
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Hexanitrohexaazaisowurtzitane : ウィキペディア英語版
Hexanitrohexaazaisowurtzitane

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Hexanitrohexaazaisowurtzitane , also called HNIW and CL-20, is a nitroamine explosive with the formula C6H6N12O12, developed by the China Lake facility, primarily to be used in propellants. It has a better oxidizer-to-fuel ratio than conventional HMX or RDX. It produces 20% more energy than traditional HMX-based propellants, and is widely superior to conventional high-energy propellants and explosives.
While most development of CL-20 has been fielded by the Thiokol Corporation, the US Navy (through ONR) has also been interested in CL-20 for use in rocket propellants, such as for missiles, as it has lower observability characteristics such as less visible smoke.
CL-20 has not yet been fielded in any production weapons system, but is undergoing testing for stability, production capabilities, and other weapons characteristics.
== Synthesis ==

First, benzylamine (1) is condensed with glyoxal (2) under acidic and dehydrating conditions to yield the first intermediate compound.(3). Four benzyl groups selectively undergo hydrogenolysis using palladium on carbon and hydrogen. The amino groups are then acetylated during the same step using acetic anhydride as the solvent. (4). Finally, compound 4 is reacted with nitronium tetrafluoroborate and nitrosonium tetrafluoroborate, resulting in HNIW.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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