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・ Dihydrolipoyllysine-residue succinyltransferase
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Dihydropyran
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Dihydropyran : ウィキペディア英語版
Dihydropyran

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Dihydropyran is a heterocyclic compound with the formula C5H8O. The six-membered, not aromatic, ring has five carbon atoms and one oxygen atom. It contains one double bond. There are two isomers of dihydropyran that differ by the location of the double bond. 3,4-Dihydro-2''H''-pyran has a double bond at position 5; 3,6-dihydro-2''H''-pyran has the double bond at position 4.
== Nomenclature ==

In IUPAC names, "dihydro" refers to the two added hydrogen atoms needed to remove one double bond from the parent compound pyran. The numbers in front of the prefix indicate the position of the added hydrogen atoms. 〔A Guide to IUPAC Nomenclature of Organic Compounds (Recommendations 1993): (''R-3.1.2 Hydro prefixes'' )〕
The italicized capital ''H'' denotes the "indicated hydrogen", that is a second hydrogen atom present on the location where no double bond is present. The indicated hydrogen is placed just in front of the parent hydride (pyran). 〔A Guide to IUPAC Nomenclature of Organic Compounds (Recommendations 1993): (''R-1.3 Indicated Hydrogen'' )〕
Note that the position numbers of the ring-members not follow the position of the double bonds here. If also the second double bond is removed by two more hydrogen atoms we get tetrahydropyran, or oxane.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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