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DDT
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・ DDT-dehydrochlorinase
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DDT : ウィキペディア英語版
DDT

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DDT (dichlorodiphenyltrichloroethane) is a colorless, crystalline, tasteless and almost odorless organochloride known for its insecticidal properties. DDT has been formulated in almost every conceivable form, including solutions in xylene or petroleum distillates, emulsifiable concentrates, water-wettable powders, granules, aerosols, smoke candles and charges for vaporizers and lotions.
First synthesized in 1874, DDT's insecticidal action was discovered by the Swiss chemist Paul Hermann Müller in 1939. It was then used in the second half of World War II to control malaria and typhus among civilians and troops. After the war, DDT was made available for use as an agricultural insecticide and its production and use duly increased. Müller was awarded the Nobel Prize in Physiology or Medicine "for his discovery of the high efficiency of DDT as a contact poison against several arthropods" in 1948.〔(NobelPrize.org: The Nobel Prize in Physiology of Medicine 1948 ), accessed July 26, 2007.〕
In 1962, the book ''Silent Spring'' by American biologist Rachel Carson was published. It cataloged the environmental impacts of indiscriminate DDT spraying in the United States and questioned the logic of releasing large amounts of potentially dangerous chemicals into the environment without a sufficient understanding of their effects on ecology or human health. The book claimed that DDT and other pesticides had been shown to cause cancer and that their agricultural use was a threat to wildlife, particularly birds. Its publication was a seminal event for the environmental movement and resulted in a large public outcry that eventually led, in 1972, to a ban on the agricultural use of DDT in the United States. A worldwide ban on its agricultural use was later formalized under the Stockholm Convention, but its limited use in disease vector control continues to this day and remains controversial, because of its effectiveness in reducing deaths due to malaria, which is countered by environmental and health concerns.
Along with the passage of the Endangered Species Act, the US ban on DDT is cited by scientists as a major factor in the comeback of the bald eagle (the national bird of the United States) and the peregrine falcon from near-extirpation in the contiguous United States.〔(Missouri Animals of Conservation Concern ), p. 30〕
==Properties and chemistry==

DDT is similar in structure to the insecticide methoxychlor and the acaricide dicofol. Being highly hydrophobic, it is nearly insoluble in water but has good solubility in most organic solvents, fats and oils. DDT does not occur naturally, but is produced by the reaction of chloral () with chlorobenzene () in the presence of sulfuric acid as a catalyst. Trade names that DDT has been marketed under include Anofex, Cezarex, Chlorophenothane, Clofenotane, Dicophane, Dinocide, Gesarol, Guesapon, Guesarol, Gyron, Ixodex, Neocid, Neocidol and Zerdane.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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