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CIDNP : ウィキペディア英語版
CIDNP

CIDNP (chemically induced dynamic nuclear polarization), often pronounced like "kidnip", is an NMR technique that is used to study chemical reactions that involve radicals.
==Concept and experimental set-up==
The effect is detected by NMR spectroscopy, usually using 1H NMR spectrum, as enhanced absorption or emission signals ("negative peaks"). The effect arises when unpaired electrons (radicals) are generated during a chemical reaction. Because the magnetic moment of an electron is more than 600x that of a proton, the spins of many protons are polarized beyond the usual thermal Boltzmann distribution.
The CIDNP experiment is conducted within the NMR tube. The radicals are produced by thermal or photochemical reactions, usually from colligation and diffusion, or disproportionation of radical pairs.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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