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Arsine
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Arsine : ウィキペディア英語版
Arsine

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Arsine is an inorganic compound with the formula AsH3. This flammable, pyrophoric, and highly toxic gas is one of the simplest compounds of arsenic.〔 Despite its lethality, it finds some applications in the semiconductor industry and for the synthesis of organoarsenic compounds. The term ''arsine'' is commonly used to describe a class of organoarsenic compounds of the formula AsH3−xRx, where R = aryl or alkyl. For example, As(C6H5)3, called triphenylarsine, is referred to as "an arsine."
==General properties==
At its standard state, arsine is a colorless, denser-than-air gas that is slightly soluble in water (20% at 20 C) and in many organic solvents as well. Whereas arsine itself is odorless, owing to its oxidation by air it is possible to smell a slight garlic or fish-like scent when the compound is present above 0.5 ppm.〔(【引用サイトリンク】title=Medical Management Guidelines for Arsine (AsH3) )〕 This compound is generally regarded as stable, since at room temperature it decomposes only slowly. At temperatures of ca. 230 °C decomposition to arsenic and hydrogen is rapid. Several factors, such as humidity, presence of light and certain catalysts (namely aluminium) facilitate the rate of decomposition.
AsH3 is a pyramidal molecule with H–As–H angles of 91.8° and three equivalent As–H bonds, each of 1.519 Å length.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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