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・ 3-Methylcatechol
・ 3-Methylcrotonyl-CoA carboxylase deficiency
・ 3-Methylcyclopropene
・ 3-methyleneoxindole reductase
・ 3-Methylfentanyl
・ 3-Methylfuran
・ 3-Methylglutaconic acid
・ 3-Methylglutaconic aciduria
・ 3-Methylglutaconyl-CoA
・ 3-Methylheptane
・ 3-Methylhexane
・ 3-Methylmethcathinone
・ 3-Methylornithine
・ 3-Methylpentane
・ 3-Methylphenethylamine
3-Methylpyridine
・ 3-methylquercetin 7-O-methyltransferase
・ 3-Methylthiofentanyl
・ 3-Minute Rule
・ 3-Minute Warning
・ 3-Monoacetylmorphine
・ 3-Nitroaniline
・ 3-Nitrobenzaldehyde
・ 3-Nitrobenzanthrone
・ 3-Nitrobenzoic acid
・ 3-Nitrobenzyl alcohol
・ 3-Nitrochlorobenzene
・ 3-Nitrotoluene
・ 3-O-alpha-D-glucosyl-L-rhamnose phosphorylase
・ 3-O-alpha-D-mannopyranosyl-alpha-D-mannopyranose xylosylphosphotransferase


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3-Methylpyridine : ウィキペディア英語版
3-Methylpyridine

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3-Methylpyridine or 3-picoline, is an organic compound with formula 3-CH3C5H4N. It is one of three isomers of methylpyridine. This colorless liquid is a precursor to pyridine derivatives that have applications in the pharmaceutical and agricultural industries. Like pyridine, 3-methylpyridine is a colorless liquid with a strong odor. It is classified as a weak base.
==Synthesis==
3-Methylpyridine is produced industrially by the reaction of acrolein with ammonia:
:2 CH2CHCHO + NH3 → 3-CH3C5H4N + 2 H2O
This reaction is nonselective and a more efficient route starts with acrolein, propionaldehyde, and ammonia:
:CH2CHCHO + CH3CH2CHO + NH3 → 3-CH3C5H4N + 2 H2O + H2
It may also be obtained as a co-product of pyridine synthesis from acetaldehyde, formaldehyde, and ammonia via Chichibabin pyridine synthesis. Approximately 9,000,000 kilograms were produced worldwide in 1989.


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