Petrochemicals are chemical products derived from petroleum. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sources such as corn or sugar cane.
The two most common petrochemical classes are olefins (including ethylene and propylene) and aromatics (including benzene, toluene and xylene isomers). Oil refineries produce olefins and aromatics by fluid catalytic cracking of petroleum fractions. Chemical plants produce olefins by steam cracking of natural gas liquids like ethane and propane. Aromatics are produced by catalytic reforming of naphtha. Olefins and aromatics are the building-blocks for a wide range of materials such as solvents, detergents, and adhesives. Olefins are the basis for polymers and oligomers used in plastics, resins, fibers, elastomers, lubricants, and gels.
Global ethylene and propylene production are about 115 million tonnes and 70 million tonnes per annum, respectively. Aromatics production is approximately 70 million tonnes. The largest petrochemical industries are located in the USA and Western Europe; however, major growth in new production capacity is in the Middle East and Asia. There is substantial inter-regional petrochemical trade.
Primary petrochemicals are divided into three groups depending on their chemical structure:
* Olefins includes ethylene, propylene, and butadiene. Ethylene and propylene are important sources of industrial chemicals and plastics products. Butadiene is used in making synthetic rubber.
* Aromatics includes benzene, toluene, and xylenes. Benzene is a raw material for dyes and synthetic detergents, and benzene and toluene for isocyanates MDI and TDI used in making polyurethanes. Manufacturers use xylenes to produce plastics and synthetic fibers.
* Synthesis gas is a mixture of carbon monoxide and hydrogen used to make ammonia and methanol. Ammonia is used to make the fertilizer urea and methanol is used as a solvent and chemical intermediate.
The prefix "petro-" is an arbitrary abbreviation of the word "petroleum"; since "petro-" is Ancient Greek for "rock" and "oleum" means "oil". Therefore, the etymologically correct term would be "oleochemicals". However, the term oleochemical is used to describe chemicals derived from plant and animal fats.
== Sources ==
The adjacent diagram schematically depicts the major hydrocarbon sources used in producing petrochemicals are:〔〔〔(SBS Polymer Supply Outlook )〕
*Methane, ethane, propane and butanes: Obtained primarily from natural gas processing plants.
*Naphtha obtained from petroleum refineries.
*Benzene, toluene and xylenes, as a whole referred to as BTX and primarily obtained from petroleum refineries by extraction from the reformate produced in catalytic reformers.
*Gas obtained from petroleum refineries.
Methane and BTX are used directly as feedstocks for producing petrochemicals. However, the ethane, propane, butanes, naphtha and gas oil serve as optional feedstocks for steam-assisted thermal cracking plants referred to as ''steam crackers'' that produce these intermediate petrochemical feedstocks:
*Butenes and butadiene
In 2007, the amounts of ethylene and propylene produced in steam crackers were about 115 Mt (megatonnes) and 70 Mt, respectively. The output ethylene capacity of large steam crackers ranged up to as much as 1.0 – 1.5 Mt per year.〔(Steam Cracking: Ethylene Production ) (PDF page 3 of 12 pages)〕
Steam crackers are not to be confused with steam reforming plants used to produce hydrogen and ammonia.
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