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lawsonite : ウィキペディア英語版
lawsonite

Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to translucent colorless, white, and bluish to pinkish grey glassy to greasy crystals. Refractive indices are nα=1.665, nβ=1.672 - 1.676, and nγ=1.684 - 1.686. It is typically almost colorless in thin section, but some lawsonite is pleochroic from colorless to pale yellow to pale blue, depending on orientation. The mineral has a Mohs hardness of 8 and a specific gravity of 3.09. It has perfect cleavage in two directions and a brittle fracture.
Lawsonite is a metamorphic mineral typical of the blueschist facies. It also occurs as a secondary mineral in altered gabbro and diorite. Associate minerals include epidote, titanite, glaucophane, garnet and quartz. It is an uncommon constituent of eclogite.
It was first described in 1895 for occurrences in the Tiburon peninsula, Marin County, California. It was named for geologist Andrew Lawson (1861–1952) of the University of California by two of Lawson's graduate students, Charles Palache and Frederick Leslie Ransome.〔Edson S. Bastin, "Biographical Memoir of Frederick Leslie Ransome, 1868-1935", National Academy of Sciences Biographic Memoirs XXII: 156 and Charles Palache with Frederick Leslie Ransome, "Uber Lawsonit, ein neues Gesteins-bildendes Mineral aus Californien" Zeits. Krist. 24 (1896): 588-592. 〕
==Composition==
Lawsonite is a metamorphic silicate mineral related chemically and structurally to the epidote group of minerals. It is close to the ideal composition of CaAl2Si2O7(OH)2 . H2O giving it a close chemical composition with anorthite CaAl2Si2O8 (its anhydrous equivalent), yet lawsonite has greater density and a different Al coordination (Comodi et al., 1996). The substantial amount of water bound in lawsonite’s crystal structure is released during its breakdown to denser minerals during prograde metamorphism. This means lawsonite is capable of conveying appreciable water to shallow depths in subducting oceanic lithosphere (Clark et al., 2006). Experimentation on lawsonite to vary its responses at different temperatures and different pressures is among its most studied aspects, for it is these qualities that affect its abilities to carry water down to mantle depths, similar to other OH-containing phases like antigorite, talc, phengite, staurolite, and epidote (Comodi et al., 1996).

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