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Many organic carbonyls undergo decarbonylation. A common transformation involves the conversion of aldehydes to alkanes, usually catalyzed by metal complexes:〔Hartwig, J. F. Organotransition Metal Chemistry, from Bonding to Catalysis; University Science Books: New York, 2010.〕 :RCHO → RH + CO Usually decarbonylation is undesirable because a functional group is lost. These reactions proceed via metal acyl hydrides. Ketones and other carbonyl-containing functional groups are more resistant to decarbonylation than are aldehydes. The reverse reaction, the insertion of CO into a bond, is also a common and industrially relevant reaction. Decarbonylations are often in competition with the reverse carbonylation reaction. : == References == 〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「decarbonylation」の詳細全文を読む スポンサード リンク
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