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cyanide : ウィキペディア英語版
cyanide

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A cyanide is any chemical compound that contains monovalent combining group CN. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom.〔IUPAC Gold Book (''cyanides'' )〕
In inorganic cyanides, such as sodium cyanide, NaCN, this group is present as the negatively charged polyatomic cyanide ion (CN); these compounds, which are regarded as salts of hydrocyanic acid, are highly toxic. The cyanide ion is isoelectronic with carbon monoxide and with molecular nitrogen.〔Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.〕〔G. L. Miessler and D. A. Tarr "Inorganic Chemistry" 3rd Ed, Pearson/Prentice Hall publisher, ISBN 0-13-035471-6.〕 Most cyanides are highly toxic.
Organic cyanides are usually called nitriles; in these, the CN group is linked by a covalent bond to a carbon-containing group, such as methyl (CH3) in methyl cyanide (acetonitrile).
Hydrocyanic acid, also known as hydrogen cyanide, or HCN, is a highly volatile liquid used to prepare acrylonitrile, which is used in the production of acrylic fibers, synthetic rubber, and plastics. Cyanides are employed in a number of chemical processes, including fumigation, case hardening of iron and steel, electroplating, and the concentration of ores. In nature, substances yielding cyanide are present in certain seeds, such as the pit of the cherry and the seeds of apples.
==Nomenclature and etymology==

In IUPAC nomenclature, organic compounds that have a –C≡N functional group are called nitriles. Thus, nitriles are organic compounds.〔IUPAC Gold Book (''nitriles'' )〕〔NCBI-MeSH (''Nitriles'' )〕
An example of a nitrile is CH3CN, acetonitrile, also known as methyl cyanide. Nitriles usually do not release cyanide ions. A functional group with a hydroxyl and cyanide bonded to the same carbon is called cyanohydrin. Unlike nitriles, cyanohydridins do release hydrogen cyanide. In inorganic chemistry, salts containing the C≡N ion are referred to as cyanides.
The word is derived from the Greek ''kyanos'', meaning dark blue, as a result of its being first obtained by the heating of the pigment known as Prussian blue.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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